报告题目：Surface chemistry of TiO2 single crystal surfaces and thin films

报 告 人：杜英歌，Environmental Molecular Sciences Laboratory，Pacific Northwest National Laboratory

报告时间：6月12日（周二） 10:30

报告地点： 物理系三层报告厅

报告摘要：Titanium dioxide (TiO2) has been extensively studied as a catalyst for a variety of potential applications, and there is a specific need for fundamental studies to address how adsorbates interact with TiO2surfaces, and how we can tailor their structures to better harvest the catalytic and photocatalytic properties.

In the first part of this talk, I will present our scanning tunneling microscopy (STM) studies of H2O, O2, and their interactions on rutile TiO2(110) surfaces under ultra-high vacuum. By tracking the same surface area before and after molecule exposure, we study the adsorption, dissociation, diffusion, and reaction processes. We show that additional information can be derived by comparing the STM results with ensemble-averaged techniques such as temperature programmed desorption (TPD) and electron stimulated desorption (ESD). The experimental results are also compared with density functional theory (DFT) calculations for a better understanding of the reaction mechanisms. In the second part, I will present our efforts in the growth and characterization of pure and doped anatase TiO2thin films grown by molecular beam expitaxy. Structural excellent, epitaxial anatase TiO2(001) films with (4x1) surface reconstructions are grown on Nb doped SrTiO3(001) substrates. While pure anatase thin films are photoactive in the UV region, we show that controlled nitrogen doping can effectively extend the photo activity to the visible region.